By adoptting the quick freezing and thawing method, a series of experimental studies of concrete of different mix ratios subjected to different high temperatures through 40 freezing and thawing cycles have been conducted. Through compressive strength tests, concrete peak stress ,strain and elastic modulus were measured. The paper discussed the influence of different high temperature and mixture ratio on the concrete freezing and thawing properties. The analysis showed that with the increment of temperature and water-cement ratio, the peak stress and elastic modulus of the concrete decreased gradually. According to the experimental result, the formula for elastic modulus after freezing and thawing and high temperature were developed. This study may provide a theoretical basis for the design of freeze-thaw resistance of concrete withstanded high temperature.