Electrochemical methods can be used to extract chloride from concrete containing chloride ions. Electricity currents and temperature are the main factors influencing the electrochemical chloride extraction process. Excessive currents density has an effect on the performance and integrity of the steel reinforced concrete, while lower temperatures reduce chloride extraction efficiency. The influence of chloride ion transport equation and temperature on chloride ion permeability coefficient is studied in this paper. Then a finite element model of chloride ion transport was established to analyze the electrochemical chloride extraction efficiency of concrete under different currents and temperatures. The results show that the temperature has a significant impact on the chloride extraction effect, and the chloride ion permeability coefficient at the higher temperature (303.15 K) is 8.8 times of that at the lower temperature (273.15 K). As the temperature increases, the currents required to achieve the same chloride extraction effect becomes smaller, i.e. similar chloride extraction efficiency can be achieved with lower currents in a higher temperature environment.