文章摘要
隋淑梅, 尹志刚, 姜利国, 海 龙.考虑地下水温度的土壤吸附氨氮动力学行为研究Journal of Water Resources and Water Engineering[J].,2016,27(3):217-220
考虑地下水温度的土壤吸附氨氮动力学行为研究
Study on dynamic behavior of ammonia nitrogen adsorbed by soil considering groundwater temperature
  
DOI:10.11705/j.issn.1672-643X.2016.03.43
中文关键词: 氨氮  吸附动力学  地下水水温度  土壤吸附氨氮
英文关键词: ammonia nitrogen  adsorption kinetics  groundwater temperature  ammonia nitrogen adsorbed by soil
基金项目:国家自然科学基金青年基金项目(51304113)
Author NameAffiliation
SUI Shumeia, YIN Zhigangb, JIANG Liguoa, Hai Longa (辽宁工程技术大学 a力学与工程学院 b.矿业学院 辽宁 阜新 123000) 
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中文摘要:
      吸附反应是氨氮进入地下水环境后发生的重要行为,直接影响氨氮在地下水中的迁移扩散规律。本文以阜新地区粉质黏土、细砂、粗砂为例,结合北方地下水温度,分别进行了温度在5、10、15、20℃时3类典型土壤的氨氮吸附动力学行为试验研究。试验结果表明:在5~20℃范围内,温度越低,粒径越小,3类土壤対氨氮的吸附量越大;5、10、15、20℃时粉质黏土、细砂与10、15、20℃时粗砂对氨氮的吸附动力学过程均符合准二级动力学模型,5℃时粗砂对氨氮的吸附动力学过程符合准一级动力学模型,吸附过程均属于化学吸附;温度在5、10、15、20℃时细砂,粗砂的限速步骤为颗粒内扩散。
英文摘要:
      Adsorption reaction is the important behavior taken place when ammonia nitrogen enters soil,and. directly influences the dispercal law of ammonia nitrogen in groundwater.Combined north groundwater temperature ,the paper took silk clay,fine sand and coarse sand in Fuxin region for example,and respectively studied the dynamic behavior of ammonia nitrogen adsorption soil adsorption of three types of soil at 5,10,15,20℃. The experimental results show that at the temperature of 5 to 20 centigrade,the lower the temperature, the smaller the particle diameter, the greater the amount of adsorption of ammonia nitrogen in three soils;the dynamics process of sandy clay and fine sand at 5,10,15,20℃ and coarse sand at the temperature of 10,15,20℃ conform to the secondary dynamic model.The adsorption kinetics of coarse sand conform to the first-order kinetic model at the temperature of 5℃, their adsorption process belongs to chemical adsorption.The rate-limiting step of fine and coarse sand at the temperature of 5,10,15,20℃ is intraparticle diffusion.
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