文章摘要
WANG Gang,CHANG Fei,ZHANG Min.超临界CO_2制备TiO_2 MCM-41介孔分子筛及光催化性能研究Journal of Water Resources and Water Engineering[J].,2011,22(6):
超临界CO_2制备TiO_2 MCM-41介孔分子筛及光催化性能研究
Study on the photo catalysis and the TiO_2 MCM-41 molecular sieve made by the super critical CO_2
  
DOI:10.11705/j.issn.1672-643X.2011.06.236
中文关键词: 超临界二氧化碳  TiO2 MCM-41  分子筛  脱色率  
英文关键词: supercritical CO2  TiO2 MCM-41  molecular sieve  decolorization  
基金项目:上海市教育委员会科研创新项目资助(11YZ113); 上海高校选拔培养优秀青年教师科研专项基金(slg10014)
Author NameAffiliation
WANG Gang,CHANG Fei,ZHANG Min WANG Gang,CHANG Fei,ZHANG Min(School of Environment and Architecture,University of Shanghai for Science and Technology,Shanghai 200093,China) 
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中文摘要:
      在超临界二氧化碳(SC-CO2)溶媒中,以钛酸四丁酯为前驱体,利用超临界溶媒的高传质性能将钛的前驱体运送到硅基分子筛MCM-41的内壁,合成了TiO2MCM-41介孔分子筛催化剂。X-射线粉末衍射和傅立叶变换红外谱图等结果表明:二氧化钛可以很好地负载在介孔结构中并保持了原来的孔道结构。以甲基橙为模拟污染分子,紫外灯为光源,研究了催化剂用量、初始溶液pH值等条件对甲基橙脱色率的影响。该合成步骤简单,材料性能优异,具有推动光催化材料污染控制和环境修复工业化的潜力。
英文摘要:
      Mesoporous molecular sieve TiO2MCM-41 was successfully synthesized in this investigation using tetrabutyl titanate as a precursor in supercritical carbon dioxide.Titanium precursor was transported and thus dispersed uniformly into the MCM-41 molecular sieve,which was confirmed by structural characterizations of X-ray powder diffraction and FT-IR analysis.Methyl Orange was selected as a simulation pollutant to evaluate the decolorization ability of as-synthesized photocatalyst and satisfactory results were f...
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