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2                        & ' ( ) & * + , -                 2024 $
              8
            k±ù=‚ƒ{Þ߄…。Ì TCä CIP Ž%—‘                           q =qe     - γε 2                        (8)
                                                                    e
                                                                         m
            µ@ 80mg/L |, ôePöû¢x@ 75%ä 53%,                        ε=RTln(1+1/c)                         (9)
                                                                                    e
            Ð)1¢x@ 301ä 213mg/g; ˆ‰ TCä CIPŽ                       E =1/2 γ                             (10)
                                                                          槡
                                                                    S
            %—‘{¯c, Ð)1f—¯e, Ž%—‘é 500                         QQ:q @ôeÐ)1,mg/g;q@´ï|{Ð)
                                                                     m
                                                                                            e
            mg/L |Ð)1¢x@ 743 ä 794mg/g, 8| KFBC                1,mg/g;c@´ï|,mg/L;b @ Langmuir
                                                                         e
            ²E{¥­9$C’ÖHä。                                      ´ï.‰,L/g;K @Ð).‰;n @Ð)ϑ”‰;
                                                                              F
                 Ò%<¢xó†!Q(5)~(7) ð Langmuir、                  b ä K @ Temkin >».‰;R@žgá¿.‰,
                                                                T    t
            Freundlich ä TemkinYV{Ð)·»uvZè¢                    R =8.314J/(mol·K);T @Ð)·»{‘,K; γ
            £, ó†!Q(8)~(10) ð D-R(Dubinin-Radush              @ [ ¶ 1 ‚ Ð ) È { ´ µ Ð ) 1 · ¨ { . ‰,
            kevich) Ð)åYYVÐ)·»uvZ袣。                         mol/J; ε@ Polanyi Ð)Í,J/mol,E @´µ+%
                                                                    2
                                                                  2
                                                                                                 S
                      qbc                                      1,kJ/mol。
                       m
                          e
                 q =                                   (5)
                  e
                     1+bc                                          KFBCÐ) TCä CIP{ Langmuir、Freundlich、
                           e
                      1/n
                 q =c K   F                            (6)     Temkin ä D-RåÐ)YVZè°±ËÞ 14 ì
                      e
                  e
                                                               —, ² 3 @ KFBCÐ) TCä CIP {³ 4 yYVå
                     RT
                 q =     ln(Kc)                        (7)     YZèB‰。
                  e
                      b      t e
                       T





                                        N 14 KFBCu TC# CIP v"ˆ×Øýwö÷à$
                                       j 3 KFBC×Ø TCÓ CIP v•„ýw"ˆéö÷£\
                         Langmuir YV             Freundlich YV        Temkin YV             D-RYV

            0=…      q/         b/              K /                                    q/        E/
                                                 F
                      m
                                                                                                  s
                                                                                        m
                                       R 2              1/n   R 2   b T   K t  R 2                       R 2
                                  -1
                                                                                          -1
                  (mg·g ) (L·g )            (L·mg-1)                                (mg·g )(kJ·mol )
                        -1
                                                                                                     -1
              TC     920      0.0083 0.794     58.64    0.42 0.938 15.9 0.1700.818   2568.1      10.9   0.911
              CIP    1874     0.0020 0.948     12.75    0.70 0.975  9.9 0.0430.852   6615.8      8.2    0.962
                                                   2
              %² 3 *†,Freundlich >»Zè{ R ½¢x                   ;, „oÐ)·»*1·šN{US'†Ùñ¯c
            @ 0.938ä 0.975, µàÁ,Ÿ 3yYV{Zè°                     ½'†。ð D-RYV[ Langmuir YVZè°±
            ±。í„o Freundlich YVþ7èÁ-³ KFBCð                    Տ{ q, ͞ q þe, íX%Á…ž{,-/Í
                                                                      m
                                                                              m
            TCä CIP {Ð), «„o KFBCð TCä CIP{Ð                   º¨l,Langmuir YVX/ÁÐ)È\²Ej¢¯
            )ÞßX¼¢¯Suµ™Ð), ]º??Xj¢¯                            S{Ð)]Œw{, ] D-RYVX/ÁÐ)È4
            SÐ)。¤·{%<D÷ܗ,Freundlich >»Q{                      5Qºj(K{,-。™¨%<²o, Ì E ùÁ 8
                                                                                                      s
            1/n ½VD、K ½Ve, –Ð)V׊uv                [21] 。Ò     kJ/mol |, •kžÐ)@ÞO; Ì E @ 8~16kJ/mol
                                                                                             s
                         F
            %<Q,TCä CIP{ 1/n½µDÁ 1, ] K ½š                     |, –•.Ð)@Þ、 kžÐ)@k; Ì E àÁ
                                                                                                       s
                                                    F
            e, h1„o KFBC[ TCä CIP §wA·šÏ{i                     16kJ/mol |, Þß@.Ð)        [22] 。² 3 ܗ D-R
            ä2, à TC{ 1/n ½šD, „o KFBCð TCÀÁ                   YVQ{ E ¢x@ 10.9ä 8.2kJ/mol, é 8~16
                                                                         s
            øbÐ), í[ÍBQ TC{Ð)1þe{°±™                           kJ/mol §w, OÒ%<{Ð)·»•.Ð)@
            ¨l。8\,Temkin YVðÐ)‰Š{Zèk±¨                         Þ、 kžÐ)@k。
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